不(bu)銹(xiu)鋼的爐(lu)中(zhong)釬焊一般是在某種保護性氣(qi)氛(fen)下或真空中(zhong)進行,保護氣(qi)氛(fen)有氫氣(qi)、分解氨和氬氣(qi)。


 干燥的氫氣或分解氨常用做爐中釬焊不銹鋼時的還原性保護氣氛,它們可還原不銹鋼表面的氧化膜,并保護不銹鋼表面在釬焊時不再氧化。一般要求氫氣或分解氨的露點低于-40℃,但也要考慮保護氣體的露點要與釬焊溫度及母材的成分相適應。釬焊溫度越低、不銹鋼表面氧化膜越穩定,要求氫氣露點越低,見圖3-4。使用分解氨作保護氣氛時,必須保證NH3完全分解,避免殘余的NH3使不銹鋼表面氮化。


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 使(shi)用(yong)(yong)氫氣(qi)(qi)或分(fen)解氨(an)作(zuo)(zuo)保護氣(qi)(qi)氛的(de)(de)好處是:可實現釬(han)焊(han)爐(lu)的(de)(de)連續工(gong)作(zuo)(zuo),便于大批量(liang)生產(chan)(chan);釬(han)焊(han)過程中(zhong)不需(xu)(xu)使(shi)用(yong)(yong)釬(han)劑,且焊(han)后(hou)工(gong)件光亮,無需(xu)(xu)任何(he)焊(han)后(hou)工(gong)件表面清(qing)理工(gong)作(zuo)(zuo);可配合(he)選用(yong)(yong)的(de)(de)釬(han)料(liao)品(pin)種多;在(zai)批量(liang)生產(chan)(chan)條件下焊(han)接成本低。但是使(shi)用(yong)(yong)氫氣(qi)(qi)或分(fen)解氨(an)作(zuo)(zuo)保護氣(qi)(qi)氛時(shi)要注意生產(chan)(chan)安全,當空(kong)氣(qi)(qi)中(zhong)混有(you)4%~74%的(de)(de)氫氣(qi)(qi)或12.5%~27%氨(an)氣(qi)(qi)時(shi),會因燃燒而產(chan)(chan)生爆炸。


 作為(wei)惰性(xing)氣(qi)體,氬(ya)氣(qi)可用(yong)作爐中釬(han)焊不(bu)(bu)(bu)(bu)銹(xiu)(xiu)(xiu)鋼時的(de)保護氣(qi)氛。與(yu)氫氣(qi)和(he)分解(jie)氨不(bu)(bu)(bu)(bu)同,氬(ya)氣(qi)不(bu)(bu)(bu)(bu)具有還原性(xing),只是利(li)用(yong)其惰性(xing)保護不(bu)(bu)(bu)(bu)銹(xiu)(xiu)(xiu)鋼表面在釬(han)焊過程中不(bu)(bu)(bu)(bu)氧化,所以不(bu)(bu)(bu)(bu)銹(xiu)(xiu)(xiu)鋼進爐釬(han)焊前必(bi)須徹底(di)清除其表面的(de)氧化膜,并且一般(ban)要求氬(ya)氣(qi)的(de)露點低(di)于-40℃。


 使(shi)用氬(ya)氣(qi)(qi)作保護氣(qi)(qi)氛一般(ban)是因(yin)為以下某種或多種原因(yin):①. 可(ke)采用含高(gao)蒸汽壓元素(su)的(de)釬,如(ru)錳基釬料(liao)或含錳較多的(de)釬料(liao);②. 單件(jian)或小(xiao)批量釬焊(han)時(shi),設(she)備成本低;③. 不(bu)銹鋼(gang)與異種材釬焊(han)時(shi)避免某些材料(liao)與爐內氣(qi)(qi)氛的(de)反應,如(ru)在含氫(qing)(qing)氣(qi)(qi)氛中釬焊(han)連接不(bu)銹鋼(gang)與鈦合金(jin)時(shi),鈦金(jin)吸氫(qing)(qing)并(bing)與氫(qing)(qing)反應;④. 生產過程安全。


 使用氬氣作保護氣氛時,常見的做法是將真空爐抽至高真空后(10-2~10-3Pa)充入少量氬氣,關閉爐體氣閥后升溫。或者在特制的密封容器內通人流動的氬氣,將空氣趕凈后,容器放入馬弗爐內加熱。也可在趕凈空氣后,關閉氣路,容器放人馬弗爐內加熱,但在升溫過


 程中要隨(sui)時(shi)注(zhu)意容器(qi)內(nei)(nei)(nei)的壓力,當容器(qi)內(nei)(nei)(nei)壓力超過(guo)大氣(qi)壓較多(duo)時(shi)應隨(sui)時(shi)放出一(yi)些氣(qi)體(ti)(ti),以保證容器(qi)完好和生產安全。使用(yong)特制的容器(qi)還有另一(yi)個(ge)便利(li):當使用(yong)未經凈化的普通(tong)瓶裝氬(ya)氣(qi)時(shi),可向(xiang)釬(han)焊爐內(nei)(nei)(nei)通(tong)入少(shao)許BF3氣(qi)體(ti)(ti)釬(han)劑(ji),或加入少(shao)許氟(fu)(fu)硼酸鉀(jia),氟(fu)(fu)硼酸鉀(jia)在800~900℃分(fen)解(jie)產生BF3.BF3可以去除金屬表面的氧化物,促進釬(han)料(liao)的潤濕(shi)。氣(qi)體(ti)(ti)釬(han)劑(ji)的使用(yong)濃度(du)一(yi)般控制在0.1%~0.001%(體(ti)(ti)積(ji)分(fen)數),避免焊后形成殘渣。氟(fu)(fu)化物對人體(ti)(ti)有害(hai),要注(zhu)意工作場地的通(tong)風。


 在真空爐中釬焊不銹鋼是一種常用且理想的方法。釬焊不銹鋼時一般要求真空度達到10-2~10-3Pa,并且要求真空爐的氣體泄漏率小于10-2Pa/s.使用真空爐釬焊不銹鋼的好處是:可避免不銹鋼的氧化;可避免釬焊爐內氣氛對母材的不良影響;真空爐升、降溫速度慢,工件不變形或變形量很小;無論以何種方式添加釬料均不會在接頭內形成氣孔;無需消耗保護氣體;無需氣體凈化裝置;無安全隱患;帶有充氣及快冷風扇置的真空爐同樣具有較高的生產率,并可實現釬焊與焊后工件熱處理的結合。


  在氫氣或分解氨氣氛爐中釬焊不銹鋼可使用紫銅、銅基、銀基、錳基、鎳基和金基釬料。在氬氣氛爐中釬焊不銹鋼可使用銅基、銀基、錳基、金基釬料。在真空爐中釬焊不銹鋼可采用紫銅、不含易蒸發元素(Zn、Cd)或僅含少量高蒸汽壓元素(Mn)的銅基和銀基釬料、鎳基釬料和金基釬料。使用鎳基釬料釬焊不銹鋼薄件時,要選擇對母材溶蝕傾向小的釬料。


 爐中(zhong)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)時(shi)(shi)影響釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)接頭(tou)性(xing)(xing)能(neng),特別是(shi)力學性(xing)(xing)能(neng)的(de)(de)主要工(gong)藝參數(shu)包釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)溫(wen)度、保(bao)溫(wen)時(shi)(shi)間(jian)(jian)。釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)溫(wen)度一(yi)(yi)(yi)(yi)般選(xuan)擇在(zai)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)料液相線溫(wen)度以(yi)上50~100℃,保(bao)溫(wen)時(shi)(shi)間(jian)(jian)在(zai)5~10min.當(dang)(dang)工(gong)件(jian)較(jiao)大時(shi)(shi),可在(zai)升溫(wen)過程中(zhong)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)料固相線溫(wen)度以(yi)下(xia)某溫(wen)度保(bao)溫(wen)一(yi)(yi)(yi)(yi)段(duan)時(shi)(shi)間(jian)(jian),確保(bao)工(gong)件(jian)溫(wen)度均勻。使用(yong)鎳基釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)料時(shi)(shi),除了(le)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)溫(wen)度和保(bao)溫(wen)時(shi)(shi)間(jian)(jian)外(wai),釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)隙也是(shi)接頭(tou)強度和塑性(xing)(xing)的(de)(de)決定(ding)因素(su)之一(yi)(yi)(yi)(yi)。圖3-5、圖3-6顯(xian)示了(le)三種鎳基釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)料釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)不銹(xiu)鋼(gang)時(shi)(shi)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)接頭(tou)強度與釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)隙的(de)(de)關(guan)系。為降低釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)料的(de)(de)熔點,鎳基釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)料中(zhong)含有較(jiao)多的(de)(de)硼(peng)、硅(gui)、磷(lin),它們在(zai)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)料組織中(zhong)以(yi)脆(cui)性(xing)(xing)的(de)(de)硼(peng)化物(wu)、硅(gui)化物(wu)、磷(lin)化物(wu)形式存在(zai)。釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)時(shi)(shi)在(zai)一(yi)(yi)(yi)(yi)定(ding)的(de)(de)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)溫(wen)度和保(bao)溫(wen)時(shi)(shi)間(jian)(jian)下(xia),當(dang)(dang)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)隙小于某一(yi)(yi)(yi)(yi)數(shu)值,硼(peng)、硅(gui)、磷(lin)向母材擴(kuo)(kuo)散充分,凝(ning)固后釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)組織為鎳基固溶體,釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)強度高(gao)、塑性(xing)(xing)好,此數(shu)值稱作(zuo)該釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)料在(zai)此釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)溫(wen)度和保(bao)溫(wen)時(shi)(shi)間(jian)(jian)下(xia)的(de)(de)最(zui)大釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)焊(han)(han)(han)(han)(han)間(jian)(jian)隙。當(dang)(dang)釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)間(jian)(jian)隙超過最(zui)大間(jian)(jian)隙,釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)中(zhong)硼(peng)、硅(gui)、磷(lin)向母材擴(kuo)(kuo)散不充分,釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)中(zhong)會存在(zai)脆(cui)性(xing)(xing)化合物(wu),釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)的(de)(de)強度和塑性(xing)(xing)都會下(xia)降。而且(qie)在(zai)一(yi)(yi)(yi)(yi)定(ding)范(fan)圍內(nei),釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)越(yue)寬,釬(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)(han)縫(feng)(feng)中(zhong)脆(cui)性(xing)(xing)相越(yue)多,接頭(tou)的(de)(de)強度和塑性(xing)(xing)越(yue)低。


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 在釬(han)焊實際部件時,有時部件加工精度或裝配精度很(hen)難(nan)保(bao)證釬(han)縫(feng)間(jian)(jian)(jian)隙很(hen)小(xiao),適當(dang)地提高(gao)釬(han)焊溫(wen)(wen)(wen)度或延長保(bao)溫(wen)(wen)(wen)時間(jian)(jian)(jian)可增大(da)(da)最大(da)(da)釬(han)焊間(jian)(jian)(jian)隙,見(jian)圖3-7。當(dang)在高(gao)溫(wen)(wen)(wen)下長時間(jian)(jian)(jian)保(bao)溫(wen)(wen)(wen)造成母材晶粒過(guo)分(fen)長大(da)(da)或釬(han)料(liao)(liao)對母材溶(rong)蝕過(guo)度時,也可在焊后接(jie)頭(tou)冷卻到某一較低溫(wen)(wen)(wen)度保(bao)溫(wen)(wen)(wen),通過(guo)擴(kuo)散(san)消除釬(han)縫(feng)中的脆性相而(er)增大(da)(da)最大(da)(da)釬(han)焊間(jian)(jian)(jian)隙,見(jian)圖3-8。但由于(yu)磷原子較大(da)(da),向(xiang)母材中擴(kuo)散(san)困難(nan),這些措施對Ni-Cr-P和Ni-P這類釬(han)料(liao)(liao)作(zuo)用(yong)不大(da)(da)。


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 爐中釬焊時為控制釬料不流到接頭外其他部位或造成工件與卡具的粘連,可在防止釬料潤濕處涂止焊劑。釬焊不銹鋼時可以用TiO2、Y2O3或云母粉與乙醇混和后做止焊劑。